Choppin: hate to burst your bubble, but NitroPlate no longer coats non-production headers. They only coat for header manufacturers. The headers in your picture are from The FabShop here in Indy. Our shop does now the polished ceramic coating for them.
As you said, the smoother your pipes are, the shinier they will be. The headers are polished in a vibratory polisher filled with little ceramic beads. Imperfections smaller than the smallest beads can't get polished out. Also, the farther apart the tubes are, the better the finish as you can get good spray coverage when applying, and the polishing beads can get in and around the tubes for polishing.
There is only 3 companies making the coating you are looking at. One is propriatery-Jet Hot, and the other 2 are CermaKrome by Techline, and Cerakote Glacier Chrome by NIC. All ceramic applicators are using one of these. We prefer the Techline product for the polished applications.
There are several quality shops on the west coast that apply these. Caps Brite Hot in Fresno does a lot of cermakrome and has a good reputation. There are lots of guys ceramic coating, but most don't do the polished finish due to the temps required to cure (above 650) and the polishing equipment necessary. If you want to ship them to Indy, We'd love to coat these up for you. PM me if you have any questions regarding ceramic coating.