Well, if you don't have a number off the old belt you took off, I keep a cloth tape measure in my toolbox for just a occasion. Adjust your alt. to your just under 1/2 your slot, wrap your tape around the pulleys. Don't pull too tight. I usually get 3 belts....the size that measured to, just a touch bigger and just a touch smaller.
OR are you talking about running the belt from the motor pulley straight to the water pump......you know, the ole Jump-On special???? If thats the case, depends on the motor and pulley size......